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Связующие агенты для термопластичных ДПК

В таблице приведены наименования связующих агентов, опробованных в технологии древеснополимерных композитов

Наименование группы агентов Дополн. вещество Исследователи
Органические агенты
1. Акрилаты
Glycidyl methacrylate (GMA)
Hydroxyethyl methacrylate (HEMA)
TBPB
TBPB
Takase and Shiraishi 1989
Takase and Shiraishi 1989
2. Амиды и имиды
N,N`-m-Phenylene bismaleicimide (BMI)DCPXanthos 1983; Sain and Kokta 1994
3. Ангидриды
Acetic anhydride (AA)
Alkyl succinic anhydride (ASA)
Succinic anhydride (SA)
Phthalic anhydride (PHA)
Maleic anhydride (MA)


BPO, pyridine

BPO or TBPB
Chtourou et al. 1992
Gatenholm et al. 1992, 1993
Rozman et al. 1994
Maldas and Kokta 1989, 1990c
Maldas and Kokta 1990d, 1991a, b
4. Хлортриазины и производные
2-Diallylamino 4,6-dichloro-s-triazine (AACA)
2-Octylamino 4,6-dichloro-s-triazine (OACA)
Methacrylic acid,3-((4,6-dichloro-s-triazine-2-yl) amino)propyl ester (MAA-CAAPE)
BPO
BPO
BPO
Zadorecki and Flodin 1985
Zadorecki and Flodin 1985
Zadorecki and Flodin 1985
5. Эпоксидные соединения
Butylene oxide (BO)
Propylene oxide (PO)

Rowell et al. 1982
Rowell et al. 1982
6. Изоцианаты
Ethyl isocyanate (EIC)Raj et al. 1988; Maldas and Kokta 1991b
Hexamethylene diisocyanate (HMDIC) Raj et al. 1988; Maldas and Kokta 1991b; Gatenholm et al. 1992
Poly[ehtylene(polyphenyl isocayanate)] (PEPPIC)Selke et al. 1990
Poly[methylene(polyphenyl isocyanate)] (PMPPIC)DCPMaldas et al. 1989a, b; Maldas and Kokta 1989, 1990a, b, 1991a; Raj et al. 1988
Toluene 2,4-diisocyanate (TDIC) Raj et al. 1988; Kokta et al. 1990a
7. Органические кислоты
Abietic acid (ABAC)
Linoleic acid (LAC)

Kokta et al. 1990b
Kokta et al. 1990b
8. Мономеры
Acrylonitrile (AN) илиKenaga et al. 1962; Kent et al. 1962;
Butyl acrylate (BA)CS2/H2O2/Fe2+Ramalingam et al. 1963; Meyer 1965,1981;
Epoxylpropyl mechacrylate (EPMA)илиEllwood et al. 1972; Maldas et al. 1988, 1989a;
Methacrylic acid (MAA) N2/H2O2/(CH3)2SO4Maldas and Kokta 1990d;
Methyl methacrylate (MMA) илиDaneault et al. 1989; Chen et al. 1995
Styrene Vinyl compoundsK2S2O5/H2O2 
9. Полимеры и сополимеры
Ethyl/vinyl acetate (E/VAC) Dalvag et al. 1985
Maleated polyethylene (MAPE) Sanadi et al. 1992
Maleated polypropylene (MAPP) DCP или TBPB, xyleneDalvag et al. 1985; Kishi et al. 1988; Han et al. 1989; Takase and Shiraishi 1989; Myers et al. 1991, 1993; Olsen 1991
N,N’-m-Phenylene bismaleicimide modified polypropylene (BPP)Sain et al. 1993
Polymethacrylic acid (PMAA) Liang et al. 1994
Polystyrene/polymethacrylic acid (PS-PMAA) Liang et al. 1994
Polyvinyl acetate (PVAC) Liang et al. 1994
Mono- and dimethylolmelamine resin (DMM)CH2O, CH3OH (или C2H5OH)Hua et al. 1987
Phenol-formaldehyde resin (PF)CH3OH или H2OCoran and Patel 1982; Chtourou et al. 1992; Simonsen and Rials 1992, 1996
Styrene-ethylene-butylene-styrene/maleic anhydride (SEBS-MA)Gatenholm et al. 1995; Hedenberg and Gatenholm 1995; Oksman et al.1998
Styrene/maleic anhydride (SMA)Simonsen et al. 1998
Неорганические агенты
Sodium silicate (Na2SiO3) MA или PMPPICMaldas and Kokta 1990a, d
Органо-неорганические агенты
Силаны
Vinyltri(2-methoxyethoxy) silane (A-172) CCl4, DCPBeshay et al. 1985; Maldas et al. 1988, 1989a; Raj et al. 1989, 1990; Kokta et al. 1990c
γ-Methacryloxypropyltrimethoxy silane (A-174) CCl4, DCP, CH3OHXanthos 1983; Beshay et al. 1985; Bataille et al. 1989; Maldas et al. 1989a; Raj et al. 1988, 1989; Kokta et al. 1990c
β-(3,4-Epoxy cyclohexyl)ethyltrimethoxy silane (A-186) LPO или DTBPOKokta et al. 1990c
γ-Glycidoxy propyltrimethoxy silane (A-187) LPO или DTBPOKokta et al. 1990c
γ-Aminopropyltriethoxy silane (A-1100) 2. DCP или BPO, MA, p-xyleneMaldas et al. 1988, 1989a; Bataille et al. 1989; Raj et al. 1989; Kokta et al. 1990c
Титанаты
Titanium di(dioctylpyrophosphate)oxyacetate (KR 138S)CH2Cl2Dalvag et al. 1985

Сокращения: BPO- benzoyl peroxide; DCP- dicumyl peroxide; LPO- lauroyl peroxide; TBPB- tert-butyl peroxide benzonate, DTBPO- di-tert-butyl peroxide.

Источник "Chemical Coupling in wood-polymer composites", Z.Lu, дек. 2003, часть 2 " A review of coupling agents and treatments "

Автор статьи: Абушенко Александр Викторович